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Inhalt des Dokuments

2017

Antiproliferative Copper(II) and Platinum(II) Complexes with Bidentate N,N-Donor Ligands
N. S. Sommerfeld, J. Gülzow, A. Roller, K. Cseh, M. A. Jakupec, A. Grohmann, M. Galanski, B. K. Keppler,
Eur. J. Inorg. Chem. 2017, 24, 3115–3124.

Aggregation of mononuclear copper complexes by metal-oxidation-induced ligand deprotonation
J. Gülzow, G. Hörner, E. Irran, A. Grohmann,
Inorg. Chim. Acta 2017, DOI: 10.1016/j.ica.2017.08.017.

Oxygen Delivery as a Limiting Factor in Modelling Dicopper(II) Oxidase Reactivity
J. Gülzow, G. Hörner, P. Strauch, A. Stritt, E. Irran, A. Grohmann,
Chem. Eur. J.
2017, 23, 7009–7023.

2011–2015

Controlled ligand distortion and its consequences for structure, symmetry, conformation and spin-state preferences of iron(II) complexes
N. Kroll, K. Theilacker, M. Schoknecht, D. Baabe, D. Wiedemann, M. Kaupp, A. Grohmann, G. Hörner,
Dalton Trans. 2015, 44, 19232–19247.

 

Spin-​state dynamics of a photochromic iron(II) complex and its immobilization on oxide surfaces via phenol anchors
P. Stock, N. Spintig, J. Scholz, J. D. Epping, C. Oelsner, D. Wiedemann, A. Grohmann, G. Hörner,
J. Coord. Chem. 201568, 3099–3115.

 

Thiocyanate anchors for salt-​like iron(II) complexes on Au(111)​: promises and caveats
P. Stock, A. Erbe, M. Buck, D. Wiedemann, H. Menard, G. Hoerner, A. Grohmann,
Z. Naturforsch. B: A Journal of Chemical Sciences 201469, 1164–1180.

 

Around the World in 18 Elements.
A. Grohmann
Angew. Chem. Int. Ed. 2014, 53, 10857.

 

Novel Dinuclear Redox-isomeric Complexes with a Tetrapodal Pyridine-based Ligand
M. P. Bubnov, N. A. Skorodumova, A. A. Zolotukhin, A. V. Arapova, E. V. Baranov, A. Stritt, A. Ünal, A. Grohmann, F. W. Heinemann, A. S. Bogomyakov, N. N. Smirnova, V. K. Cherkasov, G. A. Abakumov,
Z. Anorg. Allg. Chem. 2014, 640, 2177–2182.

 

3d- and 4d-Metal(II) Complexes of a Tris(pyridyl)ethane-­Derived N4 Ligand – A Structural Study and Reactivity ­Remarks
D. Wiedemann, A. Grohmann,
Z. Anorg. Allg. Chem. 2014, 640, 1632–1640.

 

Bulk spin-crossover in the complex [FeL(NCS)2] of a tris(pyridyl)ethane-derived N4-ligand—A temperature-dependent crystallographic study
D. Wiedemann, A. Grohmann,
Dalton Trans. 2014, 43, 2406–2417.

 

Copper(I) and Iron(II) Complexes of a Novel Tris(pyridyl)­ethane-Derived N4 Ligand: Aspects of Redox Behaviour and Bioinorganic Physicochemistry
D. Wiedemann, E. Świętek, W. Macyk, A. Grohmann,
Z. Anorg. Allg. Chem. 2013, 649, 1483–1490.

 

Mapping the Spin State in Spin-Crossover Complex Assemblies: Current-Imaging Tunnelling Spectroscopy (CITS)
A. Grohmann, M. Haryono, K. Student, P. Müller, M. Stocker,
Eur. J. Inorg. Chem. 2013, 662–669.

 

Copper(II), Iron(II), and Manganese(II) Complexes of 2-Methyl-2-(2-pyridinyl)-1,3-propanediamine
U. P. Chaudhuri, R. Shakya, J. M. McClain, E. L. Klein, D. R. Powell, A. Grohmann, R. P. Houser,
Polyhedron 2013, 54, 84–90.

 

Iron(II) Complexes of Two Amine/Imine N5 Chelate Ligands Containing a 1,4-Diazepane Core – To Crossover or Not To Crossover
M. Schmidt, D. Wiedemann, B. Moubaraki, N. F. Chilton, K. S. Murray, K. R. Vignesh, G. Rajaraman, A. Grohmann,
Eur. J. Inorg. Chem. 2013, 958–967.

 

High Intrinsic Barriers against Spin-State Relaxation in Iron(II)-Complex Solutions
P. Stock, T. Pędziński, N. Spintig, A. Grohmann, G. Hörner,
Chem. Eur. J. 2013, 19, 839–842.

 

Spin Crossover in a Vacuum-Deposited Submonolayer of a Molecular Iron(II) Complex
M. Bernien, D. Wiedemann, C. F. Hermanns, A. Krüger, D. Rolf, W. Kroener, P. Müller, A. Grohmann, W. Kuch,
J. Phys. Chem. Lett. 2012, 3, 3431–3434.

 

Copper Complexes of “Superpodal” Amine Ligands and Reactivity Studies towards Dioxygen
A. Jozwiuk, E. A. Ünal, S. Leopold, J. P. Boyd, M. Haryono, N. Kurowski, F. V. Escobar, P. Hildebrandt, J. Lach, F. W. Heinemann, D. Wiedemann, E. Irran, A. Grohmann,
Eur. J. Inorg. Chem. 2012, 3000–3013.

 

Tetrapodal Amidoxime Ligands I. Coordination Isomerism Due to Self-Complementary Dimerization of a Pyramidal Cobalt(III) Coordination Module
J. P. Boyd, E. Irran, A. Grohmann,
Dalton Trans. 2012, 41, 2477–2485.

 

Efficient Synthesis of Pentakis- and Tris(pyridine) Ligands
E. A. Ünal, D. Wiedemann, J. Seiffert, J. P. Boyd, A. Grohmann,
Tetrahedron Lett. 2012, 53, 54–55.

 

First-Row Transition Metal Complexes of a Novel Pentadentate Amine/Imine Ligand Containing a Hexahydropyrimidine Core
M. Schmidt, D. Wiedemann, A. Grohmann,
Inorg. Chim. Acta 2011, 374, 514–520.


Bond Activation in Iron(II)-Coordinated Polypodal Phosphane Ligands
S.-A. Gentschow, S. W. Kohl, W. Bauer, M. Hummert, A. Grohmann,
Eur. J. Inorg. Chem. 2011, 556–566.

2006–2010

Carbon-Supported Nickel Nanoparticles from a Wood Sample of the Tree Sebertia Acuminata Pierre ex. Baillon
M. Lerch, T. Ressler, F. Krumeich, J.-P. Cosson, E. Hnawia, A. Grohmann,
Aust. J. Chem. 2010, 63, 830–835.


Bond Activation in Iron(II) and Nickel(II) Complexes of Polypodal Phosphane
S.-A. Gentschow, S. W. Kohl, W. Bauer, F. W. Heinemann, D. Wiedemann, A. Grohmann,
Z. Naturforsch., B: Chem. Sci. 2010, 65, 238–250.


Tetrapodal Pentadentate Ligands: Single Site Reactivity and Bond Activation in Iron(II) Complexes
A. Grohmann,
Dalton Trans. 2010, 39, 1432–1440.


Spinzustandsmuster in oberflächenfixierten „Perlenschnüren” aus Eisen(II)-Komplexen

M. S. Alam, M. Stocker, K. Gieb, P. Müller, M. Haryono, K. Student, A. Grohmann,
Angew. Chem. 2010, 122, 1178–1182.


Spin-State Patterns in Surface-Grafted Beads of Iron(II) Complexes
M. S. Alam, M. Stocker, K. Gieb, P. Müller, M. Haryono, K. Student, A. Grohmann,
Angew. Chem. Int. Ed. 2010, 49, 1159–1163.


On the Spin Behaviour of Iron(II)-Dipyridyl-Triazine Complexes and their Performance as Thermal and Photonic Spin Switches
(s. auch Titelseite von Eur. J. Inorg. Chem. 2/2010)
S. K. Hain, F. W. Heinemann, K. Gieb, P. Müller, G. Hörner, A. Grohmann,
Eur. J. Inorg. Chem. 2010, 221–232.


„… und ehrt mir ihre Kunst!” – Evaluierung historischer und neuer Synthesewege zu 1,5-Dihydroxy-6-oxo-1,6-dihydropyridin-2-carbonsäure und 1,3-Dihydroxy-2-oxo-3-pyrrolin-4-carbonsäure
D. Wiedemann, A. Grohmann,
Z. Naturforsch., B: Chem. Sci. 2009, 64, 1276–1288.


Parallel Crystallization of a “Static” and a Spin-Crossover Polymorph of an Iron(II) Complex from the Same Solution
M. Haryono, F. W. Heinemann, K. Petukhov, K. Gieb, P. Müller, A. Grohmann,
Eur. J. Inorg. Chem. 2009, 2136–2143.


Gas-Phase C-H and N-H Bond Activation by a High Valent Nitrido-Iron Dication and <NH>-Transfer to Activated Olefins
M. Schlangen, J. Neugebauer, M. Reiher, D. Schröder, J. Pitarch López, M. Haryono, F. W. Heinemann, A. Grohmann, H. Schwarz,
J. Am. Chem. Soc. 2008, 130, 4285–4294.


Theoretical and Experimental Investigation of Novel Iron(II)-Based Spin-Crossover Compounds
I. Respondek, L. Bressel, P. Saalfrank, H. Kämpf, A. Grohmann,
Chem. Phys. 2008, 347, 514–522.


Self-Assembled Monolayers of a Bis(pyrazol-1-yl)pyridine-Substituted Thiol on Au(111)
C. Shen, M. Haryono, A. Grohmann, M. Buck, T. Weidner, N. Ballav, M. Zharnikov,
Langmuir 2008, 24, 12883–12891.


Head-to-Tail Interactions in Tyrosine/Benzophenone Dyads in the Ground and the Excited State: NMR and Laser Flash Photolysis Studies
G. Hörner, G. L. Hug, D. Pogocki, P. Filipiak, W. Bauer, A. Grohmann, A. Lammermann, T. Pedzinski, B. Marciniak,
Chem. Eur. J.
2008, 14, 7913–7929.


Room-Temperature Alkyne-Nitrile Metathesis and Unambiguous Proof for the Existence of a High-Valent Iron-Nitrido Dication in the Gas Phase
J. P. Boyd, M. Schlangen, A. Grohmann, H. Schwarz,
Helv. Chim. Acta 2008, 91, 1430–1434.


Square-Pyramidal Iron Coordination Modules as Potential Spin Switches for the Chemisorption on Gold
H. Kämpf, D. Daunke, F. W. Heinemann, A. Grohmann,
Appl. Phys. A: Mater. Sci. Process. 2008, 93, 303–311.


Carbamoyl Derivatives of a Pyridine-Based Tetraamine
A. K. Bilakhiya, F. W. Heinemann, A. Grohmann,
Z. Naturforsch., B: J. Chem. Sci. 2007, 62, 519–522.


Delocalized Mixed-Valence Bi- and Trinuclear Complexes with Short Cu-Cu Bonds
L. Yang, D. R. Powell, E. L. Klein, A. Grohmann, R. P. Houser
Inorg. Chem. 2007, 46, 6831–6833.


An “Asymmetrised” Tetrapodal Pentadentate Coordination Cap
(Abstracts of the 13th International Conference on Biological Inorganic Chemistry)

J. Seiffert, H. Kämpf, D. Häußinger, A. Grohmann,
J. Biol. Inorg. Chem. 2007, 12, S130.


Ligand Cleavage Put into Reverse: P-C Bond Breaking and Remaking in an Alkylphosphane Iron Complex
S. W. Kohl, F. W. Heinemann, M. Hummert, W. Bauer, A. Grohmann,
Chem. Eur. J. 2006, 12, 4313–4320.


A Non-Heme Dinuclear Iron(II) Complex Containing a Single, Unsupported Hydroxo Bridge
J. Pitarch López, H. Kämpf, M. Grunert, P. Gütlich, F. W. Heinemann, R. Prakash, A. Grohmann,
Chem. Commun. 2006, 1718–1720.


Tetra- and Triphosphane Pyridine Podands and their Cobalt(II) and Nickel(II)  Complexes
S. W. Kohl, F. W. Heinemann, M. Hummert, H. Weißhoff, A. Grohmann,
Eur. J. Inorg. Chem. 2006, 3901–3910.


Solvent Dependent Reactivity: Solvent Activation vs. Solvent Coordination in Alkylphosphane Iron Complexes
S. W. Kohl, F. W. Heinemann, M. Hummert, W. Bauer, A. Grohmann,
Dalton Trans. 2006, 5583–5592.

2001–2005

2-Methyl-N,N'-bis[2-(methylsulfanyl)ethyl]-2-(2-pyridyl)-N,N'-ditosylpropane-1,3-diamine
J. T. Michels, B. B. O'Malley, E. L. Klein, L. Yang, A. Grohmann, R. P. Houser,
Acta Crystallogr., Sect. E: Struct. Rep. Online 2005, 61, o3834–o3836.


A Tetraphosphane Imine Ligand Which Enforces Square-Pyramidal Coordination
C. Zimmermann, F. W. Heinemann, A. Grohmann,
Eur. J. Inorg. Chem. 2005, 3506–3512.


Unusual Oxidative Stability of a Multidentate Primary Amine Ligand: Facile Synthesis of the Oxo-Bridged Diiron(III) Complex
J. Pitarch López, F. W. Heinemann, A. Grohmann, O. Horner, J.-M. Latour, G. Ramachandraiah,
Inorg. Chem. Commun. 2004, 7, 773–776.


The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide
J. Pitarch López, F. W. Heinemann, A. Grohmann,
Z. Naturforsch., B: J. Chem. Sci. 2004, 59, 1600–1604.


Tetrapodal Pentadentate Nitrogen Ligands: Aspects of Complex Structure and Reactivity
A. Grohmann,
Adv. Inorg. Chem.
2004, 56, 179–210.


Synthesis and Structure of High-Nuclearity Bimetallic Clusters Containing Polycyanometallate Cores capped by [NiII(pyN4)] Fragments
J. Pitarch López, F. W. Heinemann, A. Grohmann,
Z. Anorg. Allg. Chem. 2003, 629, 2449–2457.


Iron Carbonyl, Nitrosyl, and Nitro Complexes of a Tetrapodal Pentadentate Amine Ligand: Synthesis, Electronic Structure, and Nitrite Reductase-like Reactivity
J. Pitarch López, F. W. Heinemann, R. Prakash, B. A. Hess, O. Horner, C. Jeandey, J.-L. Oddou, J.-M. Latour, A. Grohmann,
Chem. Eur. J. 2002, 8, 5709–5722.


Tetrapodal Pentadentate Ligands with NS4 and NP4 Donor Sets: An Elusive Tetrathiol, and a Sterically Encumbered Tetraphosphane
C. Zimmermann, W. Bauer, F. W. Heinemann, A. Grohmann,
Z. Naturforsch., B: J. Chem. Sci. 2002, 57, 1256–1264.


Copper(II)- and Proton-Assisted Condensation Reactions of a Tetrapodal Pentaamine with Acetone: Formation of “Podand-cum-Macrocycle” Copper Complexes and a Protonated Bis(aminal)
C. Zimmermann, F. W. Heinemann, A. Grohmann,
Eur. J. Inorg. Chem. 2001, 547–555.


Enhanced Reactivity of Small Molecules at pyN4-Coordinated Complex Fragments
(Abstracts of the 10th International Conference on Bioinorganic Chemistry)
J. Pitarch López, C. Zimmermann, F. W. Heinemann, A. Grohmann,
J. Inorg. Biochem. 2001, 86, 380.

1996–2000

The Elusive Structures of Pentakis[(triphenylphosphine)gold]ammonium(2+) Bis[tetrafluoroborate(1–)]
A. Schier, A. Grohmann, J. M. López de Luzuriaga, H. Schmidbaur,
Inorg. Chem. 2000, 39, 547–554.


Spontaneous Assembly of a Schiff Base Tetramacrocycle
S. Schmidt, W. Bauer, F. W. Heinemann, H. Lanig, A. Grohmann,
Angew. Chem. 2000, 112, 950–953; Angew. Chem., Int. Ed. 2000, 39, 913–916.


Molecular Dynamics of a Schiff Base Tetramacrocycle Studied by NMR and MD Simulations
A. Grohmann, H. Lanig, W. Bauer, S. Schmidt, F. W. Heinemann,
J. Mol. Model. 2000, 6, 119–125.


A Structurally Characterised Pair of Dicobalt(III) Peroxo/Superoxo Complexes with C2-Symmetrical Tetrapodal Pentadentate Amine Ligands, and Some Reactivity en route
S. Schmidt, F. W. Heinemann, A. Grohmann,
Eur. J. Inorg. Chem. 2000, 1657–1667.


Uniform Sidearm Derivatisations in a Tetrapodal Pentaamine: Ligands with NN4O4 Donor Sets, and a Bis(Ferrocenecarbaldehyde) Aminal
C. Dietz, F. W. Heinemann, A. Grohmann,
Z. Naturforsch., B: J. Chem. Sci. 2000, 55, 1037–1044.


The Methylcobalt(III) Complex of a Tetrapodal Pentadentate Amine Ligand, 2,6-Bis(1',3'-diamino-2'-methyl-prop-2'-yl)pyridine
A. Grohmann, F. W. Heinemann, P. Kofod,
Inorg. Chim. Acta 1999, 286, 98–102.


Kinetics and Mechanism of Base Hydrolysis in Cobalt(III) Complexes – The Case of a Complex CoLCl2+ where L has the Novel Topology of a Square-Pyramidal NN4 Coordination Cap
T. Poth, H. Paulus, H. Elias, R. van Eldik, A. Grohmann,
Eur. J. Inorg. Chem. 1999, 643–650.


“Embroidered” Square Pyramidal Coordination Caps for Nickel(II): Mono-, Di- and Tetrafunctionalisation of a Tetrapodal Pentadentate Ligand with an NN4 Donor Set
C. Dietz, F. W. Heinemann, A. Grohmann,
Eur. J. Inorg. Chem. 1999, 2147–2156.


Pyridine-Derived Tetrapodal Ligands with NO4 and NN4 Donor Sets
S. Schmidt, L. Omnès, F. W. Heinemann, J. Kuhnigk, C. Krüger, A. Grohmann,
Z. Naturforsch., B: J. Chem. Sci. 1998, 53, 946–954.


Conformational Flexibility of the Square-Pyramidal Coordination Cap in a Series of Octahedral Nickel(II) Pentaamine Complexes. Magnetochemical Characterization of the Singly µ-Cl-Bridged Nickel(II) Dimer [(pyN4)Ni–Cl–Ni(pyN4)](PF6)3 (pyN4 = 2,6-Bis(1',3'-diamino-2'-methylprop-2'-yl)pyridine)
C. Dietz, F. W. Heinemann, J. Kuhnigk, C. Krüger, M. Gerdan, A. X. Trautwein, A. Grohmann,
Eur. J. Inorg. Chem. 1998, 1041–1049.


A Solid-State NMR Study of Tungsten Methyl Group Dynamics in [W(η5-C5Me5)Me4](PF6)
D. C. Maus, V. Copie, B. Q. Sun, J. M. Griffiths, R. G. Griffin, S. F. Luo, R. R.       Schrock, A. H. Liu, S. W. Seidel, W. M. Davis, A. Grohmann,
J. Am. Chem. Soc. 1996, 118, 5665–5671.


A Square Pyramidal Coordination Cap: The Co(III) Complex of a Novel Tetrapodal Pentadentate Ligand with an NN4 Donor Set
A. Grohmann, F. Knoch,
Inorg. Chem. 1996, 35, 7932–7934.



A. Grohmann,
Nachr. Chem. Techn. Lab. 1996, 44, 130–135.

1991–1995


A. Grohmann,
Nachr. Chem. Techn. Lab. 1995, 43, 124–132.


Gold in Chains: Self-Assembly of a Gold(I) Catenane
A. Grohmann,
Angew. Chem. 1995, 107, 2279–2281; Angew. Chem., Int. Ed. 1995, 34, 2107–2109.


Reversible Intramolecular Base Stabilization in Silylene (Silanediyl) Complexes – Surprising Reactivity for Silylene Coordination Compounds with a Dynamic N···Si···N Bond
H. Handwerker, C. Leis, R. Probst, P. Bissinger, A. Grohmann, P. Kiprof, E.         Herdtweck, J. Blümel, N. Auner, C. Zybill,
Organometallics 1993, 12, 2162–2176.



A. Grohmann, J. Riede, H. Schmidbaur,
Z. Naturforsch., B: J. Chem. Sci. 1992, 47, 1255–1260.


Imido-Gold Clusters: Synthesis and Magnetic Resonance Spectroscopy of “Gilded” Diamines
A. Grohmann, H. Schmidbaur,
Inorg. Chem. 1992, 31, 3378–3380.



A. Grohmann, J. Riede, H. Schmidbaur,
Abstr. Pap. Am. Chem. Soc. 1991, 202, INOR-367.


Gilding Primary Amines: Formation of Organotris(triphenylphosphineaurio)ammonium Tetrafluoroborates [(AuPPh3)3NR]+BF4; Crystal Structures where R = But or C6H11
A. Grohmann, J. Riede, H. Schmidbaur,
J. Chem. Soc., Dalton Trans. 1991, 783–787.

1988–1990

New Ruthenium Carboxylate Complexes Having a 1-5-η5-Cyclooctadienyl Ligand
K. Osakada, A. Grohmann, A. Yamamoto,
Organometallics 1990, 9, 2092–2096.


Electron-Deficient Bonding at Pentacoordinate Nitrogen
A. Grohmann, J. Riede, H. Schmidbaur,
Nature 1990, 345, 140–142.


Further Evidence for Attractive Interactions between Gold(I) Centers in Binuclear Complexes
H. Schmidbaur, K. Dziwok, A. Grohmann, G. Müller,
Chem. Ber. 1989, 122, 893–895.


Dialkyl(η5-cyclopentadienyl)chromium Derivatives with Extreme Values of 1(2)H-NMR Parameters
A. Grohmann, F. H. Köhler, G. Müller, H. Zeh,
Chem. Ber. 1989, 122, 897–899.


Phosphane-Borane Chemistry. Open-Chain and Cyclic Phosphane-Boranes Based on Tetramethyldiphosphane
H. Schmidbaur, T. Wimmer, A. Grohmann, O. Steigelmann, G. Müller,
Chem. Ber. 1989, 122, 1607–1612.


Synthesis, Structure, and Bonding of the Cation [{(C6H5)3PAu}5C]+
F. Scherbaum, A. Grohmann, G. Müller, H. Schmidbaur,
Angew. Chem. 1989, 101, 464–466; Angew. Chem., Int. Ed. 1989, 28, 463–465.


“Aurophilicity” as a Consequence of Relativistic Effects: The Hexakis(triphenylphosphaneaurio)methane Dication [(Ph3PAu)6C]2+
F. Scherbaum, A. Grohmann, B. Huber, C. Krüger, H. Schmidbaur,
Angew. Chem. 1988, 100, 1602–1604; Angew. Chem., Int. Ed. 1988, 27, 1544–1546.

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Prof. Dr. Andreas Grohmann
Institut für Chemie
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Prof. Dr. Andreas Grohmann
Bioanorganische Chemie
Institut für Chemie
Gebäude C
Raum C 107
Straße des 17. Juni 115
10623 Berlin